Interplay between the ionic and electronic density profiles in liquid metal surfaces

First principles molecular dynamics simulations have been performed for the liquid-vapor interfaces of liquid Li, Mg, Al and Si. We analize the oscillatory ionic and valence electronic density profiles obtained, their wavelengths and the mechanisms behind their relative phase-shift.Comment: Accepted for publication in Journal of Chemical Physic

Use of high-dimensional spectral data to evaluate organic matter, reflectance relationships in soils

Recent breakthroughs in remote sensing technology have led to the development of a spaceborne high spectral resolution imaging sensor, HIRIS, to be launched in the mid-1990s for observation of earth surface features. The effects of organic carbon content on soil reflectance over the spectral range of HIRIS, and to examine the contributions of humic and fulvic acid fractions to soil reflectance was evaluated. Organic matter from four Indiana agricultural soils was extracted, fractionated, and purified, and six individual components of each soil were isolated and prepared for spectral analysis. The four soils, ranging in organic carbon content from 0.99 percent, represented various combinations of genetic parameters such as parent material, age, drainage, and native vegetation. An experimental procedure was developed to measure reflectance of very small soil and organic component samples in the laboratory, simulating the spectral coverage and resolution of the HIRIS sensor. Reflectance in 210 narrow (10 nm) bands was measured using the CARY 17D spectrophotometer over the 400 to 2500 nm wavelength range. Reflectance data were analyzed statistically to determine the regions of the reflective spectrum which provided useful information about soil organic matter content and composition. Wavebands providing significant information about soil organic carbon content were located in all three major regions of the reflective spectrum: visible, near infrared, and middle infrared. The purified humic acid fractions of the four soils were separable in six bands in the 1600 to 2400 nm range, suggesting that longwave middle infrared reflectance may be useful as a non-destructive laboratory technique for humic acid characterization

Surface structure in simple liquid metals. An orbital free first principles study

Molecular dynamics simulations of the liquid-vapour interfaces in simple sp-bonded liquid metals have been performed using first principles methods. Results are presented for liquid Li, Na, K, Rb, Cs, Mg, Ba, Al, Tl, and Si at thermodynamic conditions near their respective triple points, for samples of 2000 particles in a slab geometry. The longitudinal ionic density profiles exhibit a pronounced stratification extending several atomic diameters into the bulk, which is a feature already experimentally observed in liquid K, Ga, In, Sn and Hg. The wavelength of the ionic oscillations shows a good scaling with the radii of the associated Wigner-Seitz spheres. The structural rearrangements at the interface are analyzed in terms of the transverse pair correlation function, the coordination number and the bond-angle distribution between nearest neighbors. The valence electronic density profile also shows (weaker) oscillations whose phase, with respect to those of the ionic profile, changes from opposite phase in the alkalis to almost in-phase for Si.Comment: 16 pages, 18 figures, 5 tables. Submitted to Phys. Rev.

Is Virtual Cognitive Stimulation Therapy the Future for People with Dementia? An Audit of UK NHS Memory Clinics During the COVID-19 Pandemic

Access to psychosocial interventions for people with dementia, such as Cognitive Stimulation Therapy (CST), has been restricted during the COVID-19 pandemic. Some services have shifted to provision via videoconferencing, but the prevalence of this is unknown. This audit aimed to understand provision of virtual CST (vCST) within National Health Service (NHS) memory clinics throughout the UK and Channel Islands and investigate plans for ongoing CST provision. A cross-sectional survey was circulated to NHS memory clinics, which included closed and open-ended questions to generate quantitative and qualitative data. Thirty-three memory clinics responded to the survey. During the pandemic, 55% of respondents offered vCST, whereas 45% offered no CST. Of those offering vCST, 80% plan to continue with a hybrid model of separate face-to-face and vCST groups, whilst 20% intend to deliver face-to-face CST only. Reported positive aspects of vCST were participant and staff enjoyment, perceived improved digital confidence in participants, and improved accessibility for those who cannot attend face-to-face groups. Negative aspects related to digital poverty, limited digital literacy, support needed from carers, the impact of sensory impairment on engagement, and staff time commitment. Virtual CST has been a feasible alternative to face-to-face services during the pandemic but should not completely replace in-person groups. A hybrid approach would increase accessibility for all. Future research should explore efficacy of vCST and seek to understand patterns of exclusion from such digital interventions

Fatty Acid Metabolism on Pasture- and Feedlot-Finished Cattle

Feeding high-grain diets to finishing beef cattle results in high proportions of saturated fatty acids (SFA) in the beef, which is considered to confer negative impacts on human health. In contrast, pasture-finished cattle produce lower proportion of SFA, greater n-3 and less n-6 polyunsaturated fatty acids (PUFA), and higher conjugated linoleic acids (CLA) compared to high grain-finished beef (Noviandi et al. 2012). Increased n-3 PUFA, especially C18:3 n-3, can reduce the risk of heart disease, hypertension, inflammation, and mammary cancer, and lower cholesterol concentration in blood (De Deckere et al. 1998; Tapiero et al. 2002). Nitrogen fertilisation can increase biomass production and nitrogen (N) concentration of tall fescue (TF; Festuca arundinacea) (Berg and Sims 2000; Teuton et al. 2007), which positively affected beef cattle performance (Berg and Sims 1995). However, the metabolism of fatty acids (FA) in pasture-finished beef steers due to N fertilization on TF has not yet been studied. Therefore, the current study was performed to test a hypothesis that due to its potential impacts on nutrient and energy utilization, N fertilization would affect FA compositions in ruminal fluid, blood serum, and adipose tissue of pasture-finished beef steers. In addition, we were interested in beneficial effects of grazing steers by comparing the FA profiles between pasture- and feedlot-finished beef steers

Structural and dynamical properties of liquid Si. An orbital-free molecular dynamics study

Several static and dynamic properties of liquid silicon near melting have been determined from an orbital free {\em ab-initio} molecular dynamics simulation. The calculated static structure is in good agreement with the available X-ray and neutron diffraction data. The dynamical structure shows collective density excitations with an associated dispersion relation which closely follows recent experimental data. It is found that liquid silicon can not sustain the propagation of shear waves which can be related to the power spectrum of the velocity autocorrelation function. Accurate estimates have also been obtained for several transport coefficients. The overall picture is that the dynamic properties have many characteristics of the simple liquid metals although some conspicuous differences have been found.Comment: 12 pages, 11 figure

Orbital free ab initio molecular dynamics study of liquid Al near melting

Producción CientíficaThe orbital free ab initio molecular dynamics method is applied to study the static and dynamic structure of liquid Al near the triple point. The method uses a new kinetic energy functional, along with a local pseudopotential constructed within the same kinetic energy functional. The results obtained for the dynamic structure factor are compared with recent experimental data

LoCuSS: Connecting the Dominance and Shape of Brightest Cluster Galaxies with the Assembly History of Massive Clusters

We study the luminosity gap, dm12, between the first and second ranked galaxies in a sample of 59 massive galaxy clusters, using data from the Hale Telescope, HST, Chandra, and Spitzer. We find that the dm12 distribution, p(dm12), is a declining function of dm12, to which we fitted a straight line: p(dm12) propto -(0.13+/-0.02)dm12. The fraction of clusters with "large" luminosity gaps is p(dm12>=1)=0.37+/-0.08, which represents a 3sigma excess over that obtained from Monte Carlo simulations of a Schechter function that matches the mean cluster galaxy luminosity function. We also identify four clusters with "extreme" luminosity gaps, dm12>=2, giving a fraction of p(dm12>=2)=0.07+0.05-0.03. More generally, large luminosity gap clusters are relatively homogeneous, with elliptical/disky brightest cluster galaxies (BCGs), cuspy gas density profiles (i.e. strong cool cores), high concentrations, and low substructure fractions. In contrast, small luminosity gap clusters are heterogeneous, spanning the full range of boxy/elliptical/disky BCG morphologies, the full range of cool core strengths and dark matter concentrations, and have large substructure fractions. Taken together, these results imply that the amplitude of the luminosity gap is a function of both the formation epoch, and the recent infall history of the cluster. "BCG dominance" is therefore a phase that a cluster may evolve through, and is not an evolutionary "cul-de-sac". We also compare our results with semi-analytic model predictions based on the Millennium Simulation. None of the models are able to reproduce all of the observational results, underlining the inability of current models to match the empirical properties of BCGs. We identify the strength of AGN feedback and the efficiency with which cluster galaxies are replenished after they merge with the BCG in each model as possible causes of these discrepancies. [Abridged]Comment: 15 pages, 12 figures, accepted for publication in MNRA